• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a method of manufacturing a conductive composite material, as well as the composite material obtainable by this method and conductive composite particles for use in this process. It also relates to a composite material comprising a composite polymer matrix enclosing a three-dimensional metal network forming a continuous conductive path.
    公开号:FR3042305A1
    申请号:FR1559719
    申请日:2015-10-13
    公开日:2017-04-14
    发明作者:Marc Audenaert；Denis Huze
    申请人:Arkema France SA；
    IPC主号:
    专利说明:

    METHOD FOR MANUFACTURING CONDUCTIVE COMPOSITE MATERIAL AND
    COMPOSITE MATERIAL SO OBTAINED
    OBJECT OF THE INVENTION
    The present invention relates to a method of manufacturing a conductive composite material, as well as the composite material obtainable by this method and conductive composite particles for use in this process. It also relates to a composite material comprising a composite polymer matrix enclosing a three-dimensional metal network forming a continuous conductive path.
    BACKGROUND OF THE INVENTION
    Polymeric materials are of interest in many applications because of their lightness. Their mechanical properties can also be adjusted by incorporating different fillers and especially reinforcing fibers such as carbon fibers. The resulting composites thus advantageously replace the metals in many applications. It is estimated that today composite materials represent more than 25% of the mass of the structure of an Airbus A380 where they have supplanted aluminum alloys.
    However, the electrical conductivity of these composites based on carbon fibers is much lower than that of metals. These fibers have the disadvantage of creating, within the material, a conductive path that is a function of their orientation. This disadvantage is particularly pronounced in the context of the stratified structures typically used in the aeronautical field, which have an insufficient capacity to dissipate the electric current in the direction orthogonal to the plane of the folds of fibers, the electrical conductivity in this direction being typically close to that non-conductive polymer. These structures do not resist enough to lightning. Indeed, an aircraft hit by lightning must be able to evacuate and thus conduct a current of the order of 105 amperes, without too large differences in potential may appear, likely to cause delamination of the aforementioned composite structures and serious damage for embedded electronic devices. It is therefore necessary to improve the electrical conductivity of these structures so that it approaches those of copper or aluminum in the direction of the stack of folds.
    To overcome the aforementioned drawbacks, it has been suggested to disperse conductive particles in the polymer matrix for impregnating the carbon fibers (EP 2,371,529 and EP 2,687,557). These conductive particles are intended to create electrical bridges on either side of the composite material obtained. They can be made of a carbon material, such as carbon black, or particles of glass or PMMA coated with conductive metal. In addition to the handling problems inherent in the use of nano-fillers such as carbon black, these conductive particles are generally difficult to disperse homogeneously within a polymer matrix because of their difference in density with the molten polymer. . It is therefore understood that the inclusion of these particles within the polymer matrix can complicate the formulation of the latter. In addition, the quantities of charges necessary to reach the percolation threshold, beyond which the composite material is conductive, can negatively affect certain mechanical properties of the material.
    The development of polymer-based conductive composite materials is also of interest in other industrial sectors than aeronautics, and in particular in the manufacture of housings intended to protect electronic devices against electrostatic charges.
    In the search for solutions aimed at rendering polymer matrices conductive, it has also been suggested to incorporate carbon nanotubes into them. These fillers have accentuated dispersion problems with respect to the conductive fillers previously discussed because of their entangled structure. In addition, although the concentration of nanotubes necessary to reach the percolation threshold is lower than that of other fillers, the nanotubes tend, at this concentration, to increase the viscosity of the matrix, which affects its flow properties. , necessary for its implementation and limits, again, its formulation.
    It is possible to overcome the aforementioned dispersion problems and to increase the electrical conductivity of the composite material by applying carbon nanotubes or carbon black around polymer particles, to form conductive composite particles which will then be aggregated into a material. conductive composite, rather than dispersing these charges in a polymer matrix. It has been proposed by Hao et al. in Materials Chemistry and
    Physics, Vol. 109, 15-19 (2008) a particular method of dry coating polyethylene particles with carbon nanotubes (CNTs) or carbon black, which is carried out under conditions leading to softening of the polymer particles and the fixing of the charges on their surface. The composite particles obtained are then compression molded to form plates.
    Although it has certain advantages, this method does not make it possible to overcome the problems of handling nanofillers and their possible impact on the environment. There is therefore still a need for an alternative method to that described above.
    SUMMARY OF THE INVENTION
    In this context, the inventors have developed a method of manufacturing a composite material using metal-coated polymer particles, not requiring the dispersion of these particles in a polymer matrix. Although this method and the particles used have similarities with those described by Hao et al., They are distinguished by the fact that the composite particles of Hao et al. have a surface consisting of an entangled CNT aggregate or agglomerated carbon black particles, and not a continuous film. The research carried out by the Applicant has made it possible to adjust the characteristics of the composite particles and the steps of the process according to the invention, in order to make it possible to reconcile two a priori contradictory requirements for metallic composite particles, namely the use of a amount of metal sufficient to reach the percolation threshold, without preventing coalescence of the polymer particles above the melting point. In addition, the process according to the invention has the advantage of not substantially modifying the mechanical properties of the polymer during the formation of the composite material. Finally, it makes it possible to overcome the constraints of formulation of the polymer matrices additive of the prior art. The object of the invention is therefore to propose a conductive composite material obtained from a polymer matrix, which offers good transverse electrical conductivity when it is in the form of a plate, as well as good mechanical properties, while being easy manufacture.
    The subject of the present invention is therefore a process for producing a conductive composite material from a composite polymer matrix, in which the composite polymer matrix is formed by aggregation of conductive composite particles consisting of particles of a polymer matrix, having a diameter d50 between 1 and 4.000 μηι, coated with a layer of electrically conductive material, characterized in that said electrically conductive material is made of at least one metal and in that the ratio of the thickness of said layer to d50 diameter of the polymer matrix particles is between 0.0025: 100 and 1.5: 100, said thickness being less than 300 nm.
    It also relates to the composite material that can be obtained by the method above.
    It also relates to a composite material comprising a composite polymer matrix containing a three-dimensional metal network forming a continuous conductive path. The subject of the invention is also conductive composite particles for use in the above process, characterized in that they consist of particles of a polymer matrix, having a diameter d50 of between 1 and 4,000 μm, coated with a layer of at least one metal having a thickness such that the ratio of the thickness of said layer to the diameter d50 of the polymer matrix particles is between 0.0025: 100 and 1.5: 100, said thickness being less than at 300 nm.
    DETAILED DESCRIPTION
    The method of manufacturing a composite material according to the invention is characterized in that it comprises a step of aggregating conductive composite particles.
    These particles may have a spherical, spheroidal or nonspherical shape. The diameter of these particles may be between 1 and 4000 μm, preferably between 5 and 1000 μm, more preferably between 10 and 500 μm, for example between 30 and 300 μm.
    In the context of this description, the term "diameter" is used to describe the diameter of the circumscribed circle of the particles. The D50 is the value of the particle size that divides the analyzed particle population into exactly two. In other words, 50% of the particles are smaller than the D50. The D50 is measured according to ISO 9276 - Parts 1 to 6: "Representation of data obtained by granulometric analysis". In the present description, a laser granulometer (for example Malvem type) is used to obtain the particle size distribution of the powder and to deduce the D50.
    Further, throughout this specification, the term "between" refers to a range including the cited boundaries.
    The conductive composite particles used according to the invention comprise a core consisting of a polymer matrix, which is coated with an envelope of at least one conductive metal.
    The polymer matrix comprises at least one thermoplastic or thermosetting polymer, which may optionally have elastomeric properties, preferably one or more thermoplastic polymer (s), advantageously non-elastomeric (s).
    Examples of thermoplastic polymers include olefin homo- and copolymers such as acrylonitrile-butadiene-styrene copolymers, polyethylene, polypropylene, polybutadiene and polybutylene; vinyl polymers such as poly (divinylbenzene) and ethylene-vinyl acetate copolymers; acrylic homo- and copolymers and alkyl poly (meth) acrylates such as poly (methyl methacrylate); homo- and copolyamides; polycarbonates; polyesters including poly (ethylene terephthalate) and poly (butylene terephthalate); polyethers such as poly (phenylene ether) and poly (oxymethylene); polystyrene and styrene / acrylonitrile copolymers; copolymers of styrene and maleic anhydride; polyvinyl chloride; fluorinated polymers such as polyvinylidene fluoride, polytetrafluoroethylene and polychlorotrifluoroethylene; thermoplastic polyurethanes; polyetheretherketone (PEEK) and polyetherketoneketone (PEKK); polyetherimide; polysulfone; poly (phenylene sulfide); cellulose acetate; and their mixtures.
    According to a preferred embodiment of the invention, the polymer is chosen from polyamides and polyketones.
    Polyamides include homopolyamides and copolyamides.
    Among the homopolyamides (PA), there may be mentioned PA-6, PA-11 and PA-12, obtained by polymerization of an amino acid or a lactam, PA-6.6, PA-4.6, PA-6.10, PA-6.12, PA-6.14, PA 6-18, PA-10.10 and PA-10.12, obtained by polycondensation of a diacid and a diamine, as well as aromatic polyamides such as polyarylamides, obtained in particular from 1,3-xylylene diamine and / or 1,4-xylylenediamine, and polyphthalamides, obtained from terephthalic and / or isophthalic acid. Some of the abovementioned polymers are especially available from the company ARKEMA under the trade name RILSAN.
    The copolyamides can be obtained from various starting materials: (i) lactams, (ii) aminocarboxylic acids or (iii) equimolar amounts of diamines and dicarboxylic acids. Obtaining a copolyamide requires choosing at least two different starting materials from those mentioned above. The copolyamide then comprises at least these two units. It can thus be a lactam and an aminocarboxylic acid having a different number of carbon atoms, or two lactams having different molecular weights, or a lactam combined with an equimolar amount of a diamine and a dicarboxylic acid. The lactams (i) may in particular be chosen from lauryllactam and / or caprolactam. The aminocarboxylic acid (ii) is advantageously chosen from α,--amino carboxylic acids, such as 11-aminoundecanoic acid or 12-aminododecanoic acid. For its part, the precursor (iii) may in particular be a combination of at least one aliphatic, cycloaliphatic or aromatic C 6 -C 36 carboxylic acid diacid, such as adipic acid, azelaic acid, sebacic acid, brassylic acid, n-dodecanedioic acid, terephthalic acid, isophthalic acid or 2,6-naphthalene dicarboxylic acid with at least one aliphatic, cycloaliphatic, arylaliphatic or aromatic C4-C22 diamine, such as hexamethylenediamine, piperazine, 2-methyl-1,5-diaminopentane, m-xylylene diamine or p-xylylenediamine, it being understood that said dicarboxylic acid (s) and diamine (s) are used, when they are present in equimolar quantity. Such copolyamides are in particular marketed under the trade name Platamid® by Arkema.
    According to one embodiment of the invention, it is possible to choose as polyamide a semi-aromatic polyamide (based on aromatic structure) and / or semi-cycloaliphatic (based on cycloaliphatic structure), preferably semi-aromatic, more particularly corresponding to one of the following formulas: polyamides comprising xT units where x is a linear aliphatic diamine C9 to C18, preferably C9, C10, C11, C12 and where T is terephthalic acid, selected from: 8. T, 9.T, 10.T, 11.T, 12.T,, 6.T / 9.T, 9.T / 10.T, 9.T / 11.T, 9.T / 12.T , 9 / 6.T, 10 / 6.T, 11 / 6.T, 12 / 6.T, 10/9. T, 10 / 10.T, 10 / 11.T, 10 / 12.T, 11 / 9.T, 11 / 10.T, 11 / 11.T, 11 / 12.T, 12 / 9.T, 12 / 10.T, 12 / 11.T, 12 / 12.T, 6.10 / 6.T, 6.12 / 6.T, 9.10 / 6.T, 9.12 / 6.T, 10.10 / 6.T, 10.12 / 6.T, 6.10 / 9.T, 6.12 / 9.T, 9.10 / 9.T, 9.12 / 9.T, 10.10 / 9.T 10.12 / 9.T, 6.10 / 10.T, 6.12 / 10.T , 9.10 / 10.T, 9.12 / 10.T, 10.10 / 10.T, 10.12 / 10.T, 6.10 / 12.T, 6.12 / 12.T, 9.10 / 12.T, 9.12 / 12.T, 10.10 /12.T, 11 / 6.T / 9.T, 11 / 6.T / 10.T, 11 / 6.T / 1T, 11 / 6.T / 12.T, 11 / 9.T / 10.T, 11 / 9.T / 11.T, 11 / 9.T / 12.T, 11 / 10.T / 11.T, 11 / 10.T / 12.T, 11 / 11.T / 12.T, 6.T / 10.T, 6.T / 11.T, 6.T / 12.T, 10.T / 11.T, 10.T / 12.T, 11.T / 12. T, 12 / 6.T / 10.T, 12 / 6.T / 1 T, 12 / 6.T / 12.T, 12 / 9.T / 10.T, 12 / 9.T / 11.T , 12 / 9.T / 12.T, 12 / 10.T / 11.T, 12 / 10.T / 12.T, 12 / 11.T / 12.T, Previous terpolymer polyamides with 12 / replaced by 9 /, 10 /, 6.10 /, 6.12 /, 10.10 /, 10.12 /, 9.10 / and 9.12 /, all the polyamides mentioned above where the terephthalic (T) is partially or completely replaced by the isophthalic (I), the 2,6-dicarboxylic naphthalene and / or 1,3 or 1,4 CHDA (cyclohexane dicarb oxylic), with all or part of the aliphatic diamines being replaced by cycloaliphatic diamines. all the polyamides mentioned above, with replacement of the C 7 to C 12 aliphatic diamine with a cycloaliphatic diamine among BMACM, BACM and / or IPDA and with replacement of all or part of the aromatic diacid T, with a linear or branched aliphatic diacid, This in Cis.
    In an advantageous embodiment of the invention, a semi-crystalline polyamide having a glass transition temperature of at least 100 ° C., preferably at least 120 ° C. and a lower melting temperature is used as thermoplastic polymer. at 280 ° C, these temperatures being measured by DSC according to ISO 11357. This polyamide preferably has the general formula 10.T / AT where T denotes terephthalic acid and A denotes, for example, m-xylene diamine (MXDA) or 2-methyl-pentamethylenediamine (MPMDA). This polyamide can be obtained from a reactive composition of at least one prepolymer, which is a precursor of said polyamide, bearing two terminal functions (typically NH 2 and COOH) co-reactive with each other by condensation, or two identical terminal functions ( typically NH 2 or COOH) capable of reacting with terminal functions carried by another prepolymer mixed therewith (typically COOH or NH 2). Alternatively, said polyamide may be obtained by mixing said precursors in the presence of a monomeric chain extender carrying two terminal functions of the oxazoline, epoxy or isocyanate type.
    Examples of thermosetting polymers which may be used include epoxy resins, unsaturated polyesters, phenolic resins, melamine-formaldehyde resins and polyimides, provided they are in solid form at room temperature (25 ° C.). Epoxy resins are preferred for use in this invention.
    In addition to the above polymers, the polymer matrix used according to the invention may also optionally contain one or more additives chosen from: electrically conductive fillers, hardening agents, plasticizers, lubricants, pigments, dyes, stabilizers anti-UV, anti-oxygen and / or thermal, anti-shock agents, reinforcing fillers, antistatic agents, fungicides, flame retardants and mixtures thereof. According to a preferred embodiment of the invention, it contains expanded graphite intended to improve its thermal conductivity. The reinforcing fillers are particulate materials in the form of inclusions or fibers, intended to improve the properties of the matrix. Examples of such materials are ceramic, organic, inorganic and metallic fibers, as well as carbon nanotubes. It is preferred according to the invention that the polymeric matrix contains one or more electrically conductive fillers, such as graphite.
    As indicated above, the particles used according to the invention are coated with a layer of metallic conductive material.
    Examples of metals which can be used in the present invention include silver, gold, nickel, copper, platinum, tin, titanium, cobalt, zinc, iron, chromium, aluminum, as well as their alloys, preferably gold, silver, nickel, copper, platinum, tin and titanium and more preferably silver. The application of the metal coating to the polymer particles can be done by different methods such as physical vapor deposition (PVD), chemical vapor deposition (CVD) and auto-catalytic deposition (electroless plating). It is preferred in this invention that the conductive composite particles are obtained by vapor deposition of at least one metal on the surface of the polymer matrix particles. In the CVD process, an organometallic compound can be heated to vapor and then entrained in a fluidized bed reactor containing the polymer particles, thereby decomposing the organometallic precursor and depositing the metal on the particles. of polymer. The temperature and the duration of the treatment, as well as the amount of precursor, make it possible to control the thickness of the deposit. In the PVD process, a metal precursor of the metal to be deposited can be evaporated by electron bombardment, Joule effect, induction, electric arc or ion beam. Alternatively, the deposition of the metal can be carried out by sputtering under vacuum or by ion deposition. Those skilled in the art will be able to adjust the parameters of these methods to obtain a metal layer having the desired thickness. It is preferred in this invention to use a CVD process.
    The amount of metal deposited on the polymer matrix particles may represent from 1 to 25% by weight, preferably from 5 to 20% by weight, relative to the total weight of the particles, provided that the metal layer has a thickness less than 300 nm and that the ratio of the thickness of said layer to the diameter d50 of the polymer matrix particles is between 0.0025: 100 and 1.5: 100, preferably between 0.005: 100 and 1: 100 and better still between 0.1: 100 and 0.5: 100.
    In the method according to the invention, the composite particles described above are aggregated, preferably by contacting said particles under low-shear conditions, at a temperature at which the polymer matrix is at least partially melted, so as to coalescing said particles. A composite polymer matrix is thus obtained containing a three-dimensional metal network forming a continuous conductive path.
    It is thus preferred not to use compounding, injection or extrusion processes of the composite particles, which generate too much shear of the powder.
    This aggregation step may, however, be carried out by any method of additive construction of parts from powder, and in particular by laser sintering (SLS) or with mask (SMS) or by compression molding of the particles to form a composite material. . This composite material can be directly obtained in the desired form or, provided that the polymer matrix comprises a thermoplastic polymer, it can be melted and subsequently shaped.
    Alternatively, the method according to the invention may comprise a step of coating a substrate with the composite particles described above, carried out before or simultaneously with the aggregation step. The substrate is preferably a fibrous substrate, which may be formed from natural or synthetic fibers such as glass, carbon, metallized polymer fibers and mixtures thereof. These fibers may be non-woven or woven, braided or otherwise knitted and be in the form of a wick, rope, web or ribbon, for example. In the present invention, it is preferred that the substrate consists of a web of carbon fibers. According to one embodiment, the coating and aggregation steps can be carried out simultaneously by dipping in a fluidized bed. In this case, the substrate is raised to a temperature above the melting temperature of the polymer forming the core of the particles, before the particles are applied to its surface. According to another embodiment, the coating step may be a step of dry impregnation of the substrate, in particular by electrostatic spraying, and the aggregation step may then comprise the heat treatment of the impregnated substrate, for example by infra-red heating or a convection oven.
    In the above variant, the resulting composite material constitutes a prepreg substrate that can be shaped according to various techniques. In particular, when it is in the form of a plate, it can be consolidated by calendering, for example. Alternatively, when it is in the form of composite fibers, they can be transformed into pieces of revolution by filament winding or profiles by pultrusion. Another method of shaping that can be implemented is the method of placing fibers or ribbons. The devices allowing the implementation of these methods may include means of coating and heating (aggregation) for performing all the steps of the method according to the invention.
    It is preferred that the pre-impregnated substrate consists of a fold consisting of the fibrous substrate covered, generally on both sides, with the composite material according to the invention. Several of these folds can be superimposed on one form (mold) to form a laminate which is then baked. In the case where the conductive composite particles contain a thermosetting resin, this laminate is then generally heated and compressed to cure the resin. At the end of these steps of possible coating, aggregation and generally shaping, a composite material according to the invention is obtained.
    It can in particular be used in any application requiring a high electrical conductivity and in particular to improve the electromagnetic shielding and / or the electrostatic protection of electronic components, as well as to provide lightning protection to aeronautical parts, wind turbines, buildings, automobiles, trains or boats. In the aeronautical field, the composite material according to the invention can in particular be used for the manufacture of fuselages, wings, fins, flaps, hoods, ventral beams, air intakes, radomes or fairings.
    EXAMPLES The invention will be better understood in the light of the following examples, which are given purely by way of illustration and are not intended to limit the scope of the invention, defined by the appended claims.
    Example 1: Manufacture of a Composite Film
    Polyamide 11 (Rilsan® PA11 supplied by ARKEMA) coated with a silver layer of 8 to 10% by weight, based on the total weight of the particles, was obtained by CVD. These composite particles had a D50 diameter of 100 μm, as measured by laser particle size. The thickness of the metal coating was about 150 nm.
    These particles were applied by dipping in a fluidized bed on a silicone steel plate raised to 330 °. The resulting film had a thickness of 300 μm. It was peeled off the plate and then analyzed by scanning electron microscope. Good particle coalescence and the presence of a continuous metal network within the material have been observed.
    The electrical resistance of the film was then measured using the so-called 4-point method, which plots the measured voltage curve versus the intensity applied to the sample for four different intensity values. The slope of the line obtained corresponds to the surface electrical resistance of the film, which in this example was 4 Ohm. Its transverse resistivity was 200 Ohm-cm.
    Example 2 (Comparative): Manufacture of a Composite Film
    Composite films were prepared as described in Example 1, except that the weight fraction of silver was 15-20% instead of 8-10%. The particles obtained were coated with a silver layer having a thickness of 300 to 400 nm.
    These films were brittle and had a rough, porous appearance. Their observation under a scanning electron microscope revealed poor coalescence of the grains, which also appeared mixed with metal debris.
    Example 3: Manufacture of a Composite Plate
    Four carbon fiber reinforcements (Hexcel plain 3K HS 200 g / m2) of 195 mm wide and 295 mm long were impregnated by dusting on both sides with a powder of particles of PA11 as described in Example 1. After stacking the four folds thus obtained and applying an adhesive on the 4 sides of the stack, the latter was thermocompressed. To do this, it was placed in a mold 200 mm wide and 300 mm long, coated with a sheet of Teflon fabric on each side, then the mold was introduced into a Carver press whose trays were preheated to 290 ° C, the pressure applied to the folds being 1.7 bar. The temperature of the trays was then lowered to 250 ° C. and then, after 30 sec, the pressure was raised to 10 bars. After 15 minutes, the trays were cooled to a temperature of about 100 ° C. After demolding, a composite plate was obtained.
    The transverse resistivity of these plates, measured by the so-called four-point method, was about 3,000 Ohm-cm.
    权利要求:
    Claims (10)
    [1" id="c-fr-0001]
    A method of manufacturing a conductive composite material from a composite polymer matrix, wherein the composite polymer matrix is formed by aggregation of conductive composite particles consisting of particles of a polymer matrix, having a diameter d 50 between 1 and 4.000 μm, coated with a layer of electrically conductive material, characterized in that said electrically conductive material is made of at least one metal and in that the ratio of the thickness of said layer to the diameter d50 of the matrix particles polymer is between 0.0025: 100 and 1.5: 100, said thickness being less than 300 nm.
    [2" id="c-fr-0002]
    2. Method according to claim 1, characterized in that the aggregation of the particles is carried out by contacting said composite particles under low shear conditions, at a temperature at which the polymer matrix is at least partially melted, so as to coalescing said particles.
    [3" id="c-fr-0003]
    3. Method according to claim 2, characterized in that the aggregation of the particles is carried out by laser sintering, sintering with a mask or compression molding of the particles.
    [4" id="c-fr-0004]
    4. Method according to claim 2, characterized in that it further comprises a step of coating a substrate with said particles, performed before or simultaneously with their aggregation.
    [5" id="c-fr-0005]
    5. Method according to claim 4, characterized in that the coating and aggregation steps are carried out simultaneously by dipping in a fluidized bed.
    [6" id="c-fr-0006]
    6. Method according to claim 4, characterized in that the coating step is a step of dry impregnation of the substrate and in that the aggregation step comprises the heat treatment of the impregnated substrate.
    [7" id="c-fr-0007]
    7. Method according to any one of claims 1 to 6, characterized in that the polymer matrix comprises one or more thermoplastic polymers.
    [8" id="c-fr-0008]
    8. Method according to any one of claims 1 to 7, characterized in that said conductive composite particles are obtained by vapor deposition of at least one metal on the surface of particles consisting of a polymer matrix.
    [9" id="c-fr-0009]
    9. Composite material obtainable by the method according to any one of claims 1 to 8.
    [10" id="c-fr-0010]
    10. conductive composite particles for use in the process according to any one of claims 1 to 8, characterized in that they consist of particles of a polymer matrix, having a diameter d50 of between 1 and 4,000 pm, coated a layer of at least one metal having a thickness such that the ratio of the thickness of said layer to the diameter d50 of the polymer matrix particles is between 0.0025: 100 and 1.5: 100, said thickness being less than 300 nm.
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    法律状态:
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    2017-04-14| PLSC| Publication of the preliminary search report|Effective date: 20170414 |
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    优先权:
    申请号 | 申请日 | 专利标题
    FR1559719A|FR3042305B1|2015-10-13|2015-10-13|METHOD FOR MANUFACTURING CONDUCTIVE COMPOSITE MATERIAL AND COMPOSITE MATERIAL THUS OBTAINED|
    FR1559719|2015-10-13|FR1559719A| FR3042305B1|2015-10-13|2015-10-13|METHOD FOR MANUFACTURING CONDUCTIVE COMPOSITE MATERIAL AND COMPOSITE MATERIAL THUS OBTAINED|
    US15/768,045| US11059263B2|2015-10-13|2016-10-13|Method for producing a composite conductive material and composite material obtained in this way|
    PCT/FR2016/052641| WO2017064423A1|2015-10-13|2016-10-13|Method for producing a composite conductive material and composite material obtained in this way|
    JP2018518978A| JP6843852B2|2015-10-13|2016-10-13|A method for producing a composite conductive material and a composite material thus obtained.|
    BR112018007016A| BR112018007016A2|2015-10-13|2016-10-13|process for the manufacture of a conductive composite material and composite material obtained in this manner|
    CA3001073A| CA3001073A1|2015-10-13|2016-10-13|Method for producing a composite conductive material and composite material obtained in this way|
    EP16791658.4A| EP3362505A1|2015-10-13|2016-10-13|Method for producing a composite conductive material and composite material obtained in this way|
    CN201680059680.1A| CN108137837B|2015-10-13|2016-10-13|Method for producing a composite conductive material and composite material obtained with this method|
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